Joanna Dziadkowiec

• Dziadkowiec, Joanna & Røyne, Anja (2020). Nanoscale Forces between Basal Mica Surfaces in Dicarboxylic Acid Solutions: Implications for Clay Aggregation in the Presence of Soluble Organic Acids. Langmuir.  ISSN 0743-7463.  36(49), s 14978- 14990 . doi: 10.1021/acs.langmuir.0c02290 Full text in Research Archive.
• Dziadkowiec, Joanna; Zareeipolgardani, Bahareh; Dysthe, Dag Kristian & Røyne, Anja (2019). Nucleation in confinement generates long-range repulsion between rough calcite surfaces. Scientific Reports.  ISSN 2045-2322.  9 . doi: 10.1038/s41598-019-45163-6 Full text in Research Archive.
• Dziadkowiec, Joanna; Javadi, Shaghayegh; Bratvold, Jon E.; Nilsen, Ola & Røyne, Anja (2018). Surface Forces Apparatus Measurements of Interactions between Rough and Reactive Calcite Surfaces. Langmuir.  ISSN 0743-7463.  34((25)), s 7248- 7263 . doi: 10.1021/acs.langmuir.8b00797 Full text in Research Archive.

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• Dziadkowiec, Joanna & Røyne, Anja (2021). Do soluble organic acids bind to basal mica surfaces?. Show summary

  Soluble organic acids are constantly supplied to soils as a result of the oxidative decomposition of organic matter by the plant roots and microorganisms. These carboxylic group-bearing organic molecules can interact with soil clay minerals and affect the formation and stability of organomineral aggregates. While it has been suggested that –COOH laden organics can strongly bind to broken clay edges, less is known about how such soluble acids interact with negatively charged basal clay surfaces. This work presents a Surface Forces Apparatus (SFA) study of interactions between two mica surfaces in dicarboxylic acid molecules with 2 to 7 carbon atoms. SFA allows measuring nanoscale surface forces acting between macroscopic surfaces as a function of surface separation. Since, unlike as in atomic force microscopy, the absolute surface separation in the SFA is known, it is possible simultaneously probe the adsorption of dicarboxylic acids onto mica. The results show that significant amounts of dicarboxylic acids can adsorb on mica surfaces, but only in the presence of Ca2+ ions. Ca2+ acts as cationic bridges between the negatively charged mica surface and deprotonated –COO- functionalities. In addition, the multilayer binding of larger dicarboxylic acids (C5-C7) via an assembly of hydrophobic chains is resolved. Na+ does not promote any substantial dicarboxylic acid adsorption and induce strong repulsion between mica surfaces. In summary, although these face-specific SFA measurements show that dicarboxylic acids adsorb onto mica basal surfaces only by weak forces including electrostatic, hydrophobic, and likely hydrogen bonding, they demonstrate that even such weak outer-sphere adsorption can affect adhesion between clay surfaces and play a role in the organomineral aggregate formation. Acknowledgments: This study has been financed by the Research Council of Norway (grant No 286733) and the European Union Horizon 2020 (grant No 642976-Nano-Heal).

• Dziadkowiec, Joanna; Zareeipolgardani, Bahareh; Cheng, Hsiu-Wei; Dysthe, Dag Kristian; Røyne, Anja & Valtiner, Markus (2021). Forces between reactive surfaces. Show summary

  Adhesive and repulsive, nm-range surface forces acting between mineral grains control colloidal stability and mineral aggregation but less is known about how these forces are affected by surface reactivity and to what extent these grain-scale forces can influence various deformation processes in rocks. In this experimental work, we explore and quantify the surface forces acting between dynamic mineral surfaces that undergo recrystallization or are chemically reactive in contact with water or aqueous salt solutions. Our experimental setup consists of the surface forces apparatus (SFA) coupled with the multiple beam interferometry (MBI). This setup can excellently reproduce a typical grain contact geometry with nanometer-thin water films confined between contacting mineral grains over relatively large, micron-sized contact areas. Owing to the use of MBI, both surface growth or dissolution processes can be monitored during force measurements in real-time. As such, SFA can provide information about the links between surface reactivity and adhesive or repulsive surface forces. Using the examples of force measurements between recrystallizing or chemically reactive mineral surfaces such as carbonates, hydroxides, and silicates, we comment on the relationship between the measured surface forces and surface reactivity. We link our findings with the observed changes in mineral phases, surface topographies, or surface roughness. We also comment on how the micron-scale confinement in the SFA affects the growth and dissolution processes in contrast to less confined regions. The magnitude of the forces associated with dynamic mineral surfaces and the potential significance of these forces to macroscopic deformation processes and cohesion in rocks are discussed.

• Dziadkowiec, Joanna; Cheng, Hsiu-Wei; Røyne, Anja & Valtiner, Markus (2020). Interactions between reactive mineral surfaces studied with the surface forces apparatus.
• Dziadkowiec, Joanna; Cheng, Hsiu-Wei; Røyne, Anja & Valtiner, Markus (2020). Interfacial processes at dissimilarly charged mineral surfaces in contact – a surface forces apparatus study.
• Dziadkowiec, Joanna; Zareeipolgardani, Bahareh; Dysthe, Dag Kristian & Røyne, Anja (2020). Confined Nucleation of Calcium Carbonate Studied in the Surface Forces Apparatus.
• Haffner, Fernanda; Couturier, Marion & Dziadkowiec, Joanna (2020). Crystals: From rock candy to rock(et) science. Esperluette.  June 2020
• Dziadkowiec, Joanna (2019). (CaCO3) Nucleation in confinement.
• Dziadkowiec, Joanna (2019). Interactions between mineral surfaces studied with the surface forces apparatus.
• Dziadkowiec, Joanna; Javadi, Shaghayegh & Røyne, Anja (2019). Contacts between reactive surfaces.
• Dziadkowiec, Joanna; Zareeipolgardani, Bahareh; Bratvold, Jon E.; Nilsen, Ola; Dysthe, Dag Kristian & Røyne, Anja (2019). Long-range repulsive forces between reactive calcite surfaces are generated due to nucleation in a confined solution.
• Dziadkowiec, Joanna; Javadi, Shaghayegh; Bratvold, Jon E.; Nilsen, Ola & Røyne, Anja (2018). Adhesive and repulsive forces between calcite surfaces.
• Dziadkowiec, Joanna; Javadi, Shaghayegh; Bratvold, Jon E.; Nilsen, Ola & Røyne, Anja (2018). Nucleation in solution confined between reactive surfaces can generate long-range repulsive forces.
• Javadi, Shaghayegh; Dziadkowiec, Joanna; Røyne, Anja; Bratvold, Jon E.; Nilsen, Ola & Hiorth, Aksel (2018). Synthetic CaCO3 surfaces in aqueous solutions – AFM and Surface Force Apparatus (SFA) measurements.
• Dziadkowiec, Joanna; Javadi, Shaghayegh; Bratvold, Jon E.; Nilsen, Ola & Røyne, Anja (2017). Interactions between reactive CaCO3 surfaces in aqueous solutions -Surface Forces Apparatus measurements.
• Dziadkowiec, Joanna; Javadi, Shaghayegh & Røyne, Anja (2017). Surface Forces Apparatus measurements of interactions between rough and reactive calcite surfaces.
• Dziadkowiec, Joanna & Røyne, Anja (2017). Interactions between calcite surfaces in Surface Forces Apparatus – effect of ionic strength and dicarboxylic acids.

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