Bjørn Hauback

Professor II - Inorganic materials chemistry

Norwegian version of this page

Email bjorn.hauback@smn.uio.no

Phone +47-22856422

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Visiting address Sem Sælands vei 26 None 0371 OSLO

Postal address Postboks 1033 0315 OSLO

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Positions

PhD (Dr.ing) Norwegian Institute of Technology (NTH), Trondheim, Norway 1989. Member of IFE staff since1993.
Adjunct of Physics, University of Oslo.

Field of Expertise

Materials for storage of hydrogen, materials for ICT and energy applications, magnetic materials, nanoscience, crystallography and neutron and X-ray diffraction.

Professional membership and merits

Operating Agent for IEA Hydrogen Implementation Agreement Task 22 - "Fundamental and Applied Hydrogen Storage Materials Development" from 2006.
Member of Norwegian Academy of Technological Sciences
Member of Norwegian Physical Society
Member of International Steering Committee for the International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications
Member of Steering Committee for Synchrotron Research, Research Council of Norway
Member of organization and scientific committees in a number of national and international conferences
Referee for number of international journals including J.Mater Chem., J.Phys.Chem., J.Alloys Compd, Int.J.Hydrogen Energy, Inorg.Chem., Scr. Mater., J.Solid State Chem., J.Materials Science, Phys. Chem
Evaluator of national research projects in Germany, Iceland, UK, Netherlands, Spain, Australia

Latroche, Michel; Blanchard, Didier; Cuevas, Fermìn; El-Kharbachi, Abdelouahab; Hauback, Bjørn; Jensen, Torben R.; de Jongh, Petra E.; Kim, Sangryun; Nazer, Nazia S.; Ngene, Peter; Orimo, Shin-Ichi; Ravnsbæk, Dorthe B. & Yartys, Volodymyr (2019). Full-cell hydride-based solid-state Li batteries for energy storage. International journal of hydrogen energy. ISSN 0360-3199. . doi: https://doi.org/10.1016/j.ijhydene.2018.12.200
El-Kharbachi, Abdelouahab; Hu, Yang; Sørby, Magnus Helgerud; Mæhlen, Jan Petter; Vullum, Per Erik; Fjellvåg, Helmer & Hauback, Bjørn (2018). Reversibility of metal-hydride anodes in all-solid-state lithium secondary battery operating at room temperature. Solid State Ionics. ISSN 0167-2738. 317, s 263- 267 . doi: 10.1016/j.ssi.2018.01.037
El-Kharbachi, Abdelouahab; Hu, Yang; Sørby, Magnus Helgerud; Vullum, Per Erik; Mæhlen, Jan Petter; Fjellvåg, Helmer & Hauback, Bjørn (2018). Understanding Capacity Fading of MgH2 Conversion-Type Anodes via Structural Morphology Changes and Electrochemical Impedance. Journal of Physical Chemistry C. ISSN 1932-7447. 122(16), s 8750- 8759 . doi: 10.1021/acs.jpcc.7b12656
El-Kharbachi, Abdelouahab; Hu, Yang; Yoshida, Koji; Vajeeston, Ponniah; Kim, Sangryun; Sørby, Magnus Helgerud; Orimo, Shin-Ichi; Fjellvåg, Helmer & Hauback, Bjørn (2018). Lithium ionic conduction in composites of Li(BH4)0.75I0.25 and amorphous 0.75Li2S·0.25P2S5 for battery applications. Electrochimica Acta. ISSN 0013-4686. 278, s 332- 339 . doi: 10.1016/j.electacta.2018.05.041
El-Kharbachi, Abdelouahab; Uesato, Hiroki; Kawai, Hironori; Wenner, Sigurd; Miyaoka, Hiroki; Sørby, Magnus Helgerud; Fjellvåg, Helmer; Ichikawa, Takayuki & Hauback, Bjørn (2018). MgH2–CoO: a conversion-type composite electrode for LiBH4-based all-solid-state lithium ion batteries. RSC Advances. ISSN 2046-2069. 8(41), s 23468- 23474 . doi: 10.1039/c8ra03340d Full text in Research Archive.
Gharibdoust, SevedHosein Payandeh; Heere, Michael; Nervi, Carlo; Sørby, Magnus Helgerud; Hauback, Bjørn & Jensen, Torben R. (2018). Synthesis, structure, and polymorphic transitions of praseodymium(III) and neodymium(III) borohydride, Pr(BH4)3 and Nd(BH4)3. Dalton Transactions. ISSN 1477-9226. 47(25), s 8307- 8319 . doi: 10.1039/c8dt00118a
Guzik, Matylda N.; Echevarria-Bonet, Cristina; Riktor, Marit Dalseth; Almeida Carvalho, Patricia; Gunnæs, Anette Eleonora; Sørby, Magnus Helgerud & Hauback, Bjørn (2018). Half-Heusler phase formation and Ni atom distribution in M-Ni-Sn (M = Hf, Ti, Zr) systems. Acta Materialia. ISSN 1359-6454. 148, s 216- 224 . doi: 10.1016/j.actamat.2018.01.019
Heere, Michael; Zavorotynska, Olena; Deledda, Stefano; Sørby, Magnus Helgerud; Book, David; Steriotis, Theodore & Hauback, Bjørn (2018). Effect of additives, ball milling and isotopic exchange in porous magnesium borohydride. RSC Advances. ISSN 2046-2069. 8(49), s 27645- 27653 . doi: 10.1039/C8RA05146A Full text in Research Archive.
Liu, Yinzhe; Heere, Michael; Vasquez, Luis Contreras; Paterakis, Christos; Sørby, Magnus Helgerud; Hauback, Bjørn & Book, David (2018). Dehydrogenation and rehydrogenation of a 0.62LiBH4-0.38NaBH4 mixture with nano-sized Ni. International journal of hydrogen energy. ISSN 0360-3199. 43(34), s 16782- 16792 . doi: 10.1016/j.ijhydene.2018.04.211
Milanese, Chiara; Jensen, Torben René; Hauback, Bjørn; Pistidda, Claudio; Dornheim, Martin; Yang, Heena; Lombardo, Loris; Zuettel, Andreas; Filinchuk, Yaroslav; Ngene, Peter; Jongh, Petra de; Buckley, Craig E.; Dematteis, Erika Michela & Baricco, Marcello (2018). Complex hydrides for energy storage. International journal of hydrogen energy. ISSN 0360-3199. . doi: https://doi.org/10.1016/j.ijhydene.2018.11.208
Pal, Santosh Kumar; Frommen, Christoph; Kumar, Susmit; Hauback, Bjørn; Fjellvåg, Helmer; Woodcock, T. G.; Nielsch, K & Helgesen, Geir (2018). Comparative phase transformation and magnetocaloric effect study of Co and Mn substitution by Cu in MnCoGe compounds. Journal of Alloys and Compounds. ISSN 0925-8388. 775, s 22- 29 . doi: 10.1016/j.jallcom.2018.10.040
Qviller, Atle Jorstad; Marstein, Erik Stensrud; You, Chang Chuan; Haug, Halvard; Webster, John R.P.; Hjörvarsson, Björgvin; Frommen, Christoph & Hauback, Bjørn (2018). Hydrogen Concentration in Photovoltaic a-Si:H Annealed at Different Temperatures Measured by Neutron Reflectometry. IEEE Journal of Photovoltaics. ISSN 2156-3381. 8(4), s 1098- 1101 . doi: 10.1109/JPHOTOV.2018.2838447
Santoru, Antonio; Pistidda, Claudio; Brighi, Matteo; Chierotti, Michele R.; Heere, Michael; Karimi, Fahim; Cao, Hujun; Capurso, Giovanni; Chaudhary, Anna-Lisa; Gizer, Gökhan; Garroni, Sebastiano; Sørby, Magnus Helgerud; Hauback, Bjørn; Černý, Radovan; Klassen, Thomas & Dornheim, Martin (2018). Insights into the Rb–Mg–N–H System: an Ordered Mixed Amide/Imide Phase and a Disordered Amide/Hydride Solid Solution. Inorganic Chemistry. ISSN 0020-1669. 57(6), s 3197- 3205 . doi: 10.1021/acs.inorgchem.7b03232
Sartori, Sabrina; Guzik, Matylda N.; Knudsen, Kenneth Dahl; Sørby, Magnus Helgerud; Teprovich, Jr., Joseph A.; Zidan, Ragaiy & Hauback, Bjørn (2018). Stability and Phase Formation in the (Li/Na)6C60–H Systems Studied by Neutron Scattering. Journal of Physical Chemistry C. ISSN 1932-7447. 122(32), s 18346- 18355 . doi: 10.1021/acs.jpcc.8b05977
Sato, Toyoto; Takagi, Shigeyuki; Sørby, Magnus Helgerud; Deledda, Stefano; Hauback, Bjørn & Orimo, Shin-ichi (2018). Crystal Structural Determination of SrAlD5 with Corner-Sharing AlD6 Octahedron Chains by X-ray and Neutron Diffraction. Crystals. ISSN 2073-4352. 8(2), s 89 . doi: 10.3390/cryst8020089 Full text in Research Archive.
Weidenthaler, Claudia; Felderhoff, Michael; Bernert, Thomas; Sørby, Magnus Helgerud; Hauback, Bjørn & Krech, Daniel (2018). Synthesis, Crystal Structure Analysis and Decomposition of RbAlH4. Crystals. ISSN 2073-4352. 8(2) . doi: 10.3390/cryst8020103 Full text in Research Archive.
Amenedo, José Montero; Martinsen, Fredrik Aleksander; Lelis, Martynas; Karazhanov, Smagul; Hauback, Bjørn & Marstein, Erik Stensrud (2017). Preparation of yttrium hydride-based photochromic films by reactive magnetron sputtering. Solar Energy Materials and Solar Cells. ISSN 0927-0248. 177, s 106- 109 . doi: 10.1016/j.solmat.2017.02.001
Arbab, Shabnam; Matusiak, Barbara Szybinska; Martinsen, Fredrik Aleksander & Hauback, Bjørn (2017). The impact of advanced glazing on colour perception. Journal of the International Colour Association. ISSN 2227-1309. 17, s 50- 68 Full text in Research Archive.
Baricco, Marcello; Bang, Mads; Fichtner, Maximilian; Hauback, Bjørn; Linder, Marc; Luetto, Carlo; Moretto, Pietro & Sgroi, Mauro (2017). SSH2S: Hydrogen storage in complex hydrides for an auxiliary power unit based on high temperature proton exchange membrane fuel cells. Journal of Power Sources. ISSN 0378-7753. 342, s 853- 860 . doi: 10.1016/j.jpowsour.2016.12.107
El-Kharbachi, Abdelouahab; Andersen, Hanne Flåten; Sørby, Magnus Helgerud; Vullum, Per Erik; Mæhlen, Jan Petter & Hauback, Bjørn (2017). Morphology effects in MgH2 anode for lithium ion batteries. International journal of hydrogen energy. ISSN 0360-3199. 42(35), s 22551- 22556 . doi: 10.1016/j.ijhydene.2017.04.298 Full text in Research Archive.
Floriano, R.; Deledda, Stefano; Hauback, Bjørn; Leiva, Daniel Rodrigo & Botta, W.J. (2017). Iron and niobium based additives in magnesium hydride: Microstructure and hydrogen storage properties. International journal of hydrogen energy. ISSN 0360-3199. 42(10), s 6810- 6819 . doi: 10.1016/j.ijhydene.2016.11.117
Frommen, Christoph; Sørby, Magnus Helgerud; Heere, Michael; Humphries, Terry David; Olsen, Jørn Erik & Hauback, Bjørn (2017). Rare earth borohydrides - Crystal structures and thermal properties. Energies. ISSN 1996-1073. 10(12) . doi: 10.3390/en10122115 Full text in Research Archive.
Guzik, Matylda Natalia; Golasinski, Karol M.; Pedrosa, F.J.; Jenus, Petra; Bollero, Alberto; Hauback, Bjørn & Deledda, Stefano (2017). Influence of ultra-short cryomilling on the microstructural and magnetic properties of cobalt ferrite. Journal of Alloys and Compounds. ISSN 0925-8388. 721, s 440- 448 . doi: 10.1016/j.jallcom.2017.05.290
Heere, Michael; Gharibdoust, SevedHosein Payandeh; Sørby, Magnus Helgerud; Frommen, Christoph; Jensen, Torben R. & Hauback, Bjørn (2017). In situ investigations of bimetallic potassium erbium borohydride. International journal of hydrogen energy. ISSN 0360-3199. 42(35), s 22468- 22474 . doi: 10.1016/j.ijhydene.2017.04.271
Heere, Michael; GharibDoust, Seyed Hosein Payandeh; Brighi, Matteo; Frommen, Christoph; Sørby, Magnus Helgerud; Černý, Radovan; Jensen, Torben R. & Hauback, Bjørn (2017). Hydrogen Sorption in Erbium Borohydride Composite Mixtures with LiBH4 and/or LiH. Inorganics. ISSN 2304-6740. 5(2), s 31 . doi: 10.3390/inorganics5020031 Full text in Research Archive.
Humphries, Terry David; Birkmire, Derek; McGrady, G. Sean; Hauback, Bjørn & Jensen, Craig M. (2017). Regeneration of LiAlH4 at sub-ambient temperatures studied by multinuclear NMR spectroscopy. Journal of Alloys and Compounds. ISSN 0925-8388. 723, s 1150- 1154 . doi: 10.1016/j.jallcom.2017.06.300
Nazer, N.S.; Denys, Roman Volodymyrovich; Yartys, Volodymyr; Hu, Weikang; Latroche, M.; Cuevas, F; Hauback, Bjørn; Henry, P.F. & Arnberg, Lars (2017). In operando neutron diffraction study of LaNdMgNi9H13 as a metal hydride battery anode. Journal of Power Sources. ISSN 0378-7753. 343, s 502- 512 . doi: 10.1016/j.jpowsour.2017.01.077
Paterakis, Christos; Guo, Sheng; Heere, Michael; Liu, Yinzhe; Contreras, Luis F.; Sørby, Magnus Helgerud; Hauback, Bjørn; Reed, Daniel & Book, David (2017). Study of the NaBH4–NaBr system and the behaviour of its low temperature phase transition. International journal of hydrogen energy. ISSN 0360-3199. 42(35), s 22538- 22543 . doi: 10.1016/j.ijhydene.2017.03.045
Sato, Toyoto; Ikeda, Kazutaka; Matsuo, Motoaki; Miwa, Kazutoshi; Otomo, Toshiya; Deledda, Stefano; Hauback, Bjørn C.; Li, Guanqiao; Takagi, Shigeyuki & Orimo, Shin-Ichi (2017). In-situ powder neutron diffraction study on the formation process of LaMg2NiH7. International journal of hydrogen energy. ISSN 0360-3199. 42(35), s 22449- 22453 . doi: 10.1016/j.ijhydene.2017.02.196 Full text in Research Archive.
Schrade, Matthias; Berland, Kristian; Eliassen, Simen Nut Hansen; Guzik, Matylda Natalia; Echevarria-Bonet, Cristina; Sørby, Magnus Helgerud; Jenus, Petra; Hauback, Bjørn; Tofan, Raluca; Gunnæs, Anette Eleonora; Persson, Clas; Løvvik, Ole Martin & Finstad, Terje (2017). The role of grain boundary scattering in reducing the thermal conductivity of polycrystalline XNiSn (X=Hf, Zr, Ti) half-Heusler alloys. Scientific Reports. ISSN 2045-2322. 7 . doi: 10.1038/s41598-017-14013-8 Full text in Research Archive.
Callini, Elsa; Atakli, Zuleyha Ozlem Kocabas; Hauback, Bjørn; Orimo, Shin-Ichi; Jensen, Craig; Dornheim, Martin; Grant, David; Cho, Young Whan; Chen, Ping; Hjörvarsson, Björgvin; de Jongh, Petra E.; Weidenthaler, Claudia; Baricco, Marcello; Paskevicius, Mark; Jensen, Torben R.; Bowden, Mark E; Autrey, Thomas S. & Züttel, Andreas (2016). Complex and liquid hydrides for energy storage. Applied Physics A: Materials Science & Processing. ISSN 0947-8396. 122(4) . doi: 10.1007/s00339-016-9881-5
Gharibdoust, SevedHosein Payandeh; Heere, Michael; Sørby, Magnus Helgerud; Ley, Morten B.; Ravnsbæk, Dorthe B.; Hauback, Bjørn; Černý, Radovan & Jensen, Torben R. (2016). Synthesis, structure and properties of new bimetallic sodium and potassium lanthanum borohydrides. Dalton Transactions. ISSN 1477-9226. 45(47), s 19002- 19011 . doi: 10.1039/c6dt03671f
Hauback, Bjørn & Mauroy, Henrik (2016). Neutron scattering: Introduction, In Helmut Fritzsche; Jacques Huot & Daniel Fruchart (ed.), Neutron scattering and other nuclear techniques for hydrogen in materials. Springer. ISBN 978-3-319-22791-7. Chapter 2. s 7 - 29
Heere, Michael; Payandeh GharibDoust, Seyed Hosein; Frommen, Christoph; Humphries, Terry David; Ley, Morten B.; Sørby, Magnus Helgerud; Jensen, Torben R. & Hauback, Bjørn (2016). The influence of LiH on the rehydrogenation behavior of halide free rare earth (RE) borohydrides (RE = Pr, Er). Physical Chemistry, Chemical Physics - PCCP. ISSN 1463-9076. 18(35), s 24387- 24395 . doi: 10.1039/c6cp04523e
Heere, Michael; Sørby, Magnus Helgerud; Pistidda, Claudio; Dornheim, Martin & Hauback, Bjørn (2016). Milling time effect of Reactive Hydride Composites of NaFeNaHeMgB2 investigated by in situ powder diffraction. International journal of hydrogen energy. ISSN 0360-3199. 41(30), s 13101- 13108 . doi: 10.1016/j.ijhydene.2016.05.153
Hino, Satoshi; Ichikawa, Takayuki; Kojima, Yoshitsugu; Sørby, Magnus Helgerud & Hauback, Bjørn (2016). A new complex alkali metal aluminium amide borohydride, Li2Al(ND2)4BH4: synthesis, thermal analysis and crystal structure. RSC Advances. ISSN 2046-2069. 6(34), s 28761- 28766 . doi: 10.1039/c6ra00931j Full text in Research Archive.
Miwa, Kazutoshi; Sato, Toyoto; Matsuo, Motoaki; Ikeda, Kazutaka; Otomo, Toshiya; Deledda, Stefano; Hauback, Bjørn; Li, Guanqiao; Takagi, Shigeyuki & Orimo, Shin-Ichi (2016). Metallic intermediate hydride phase of LaMg2Ni with Ni-H covalent bonding: precursor state for complex hydride formation. Journal of Physical Chemistry C. ISSN 1932-7447. 120(11), s 5926- 5931 . doi: 10.1021/acs.jpcc.6b00341
Sainudeen Nazer, Nazia; Yartys, Volodymyr; Azib, Tahar; Latroche, Michel; Cuevas, Fermìn; Forseth, Sissel; Vie, Preben Joakim Svela; Denys, Roman Volodymyrovich; Sørby, Magnus Helgerud; Hauback, Bjørn; Arnberg, Lars & Henry, Paul F. (2016). In operando neutron diffraction study of a commercial graphite/(Ni, Mn, Co) oxide-based multi-component lithium ion battery. Journal of Power Sources. ISSN 0378-7753. 326, s 93- 103 . doi: 10.1016/j.jpowsour.2016.06.105
Santoru, Antonio; Pistidda, Claudio; Sørby, Magnus Helgerud; Chierotti, Michele R.; Garroni, Sebastioni; Pinatel, Eugenio; Karimi, Fahim; Cao, Hujun; Bergemann, Nils; Le, Thi T.; Puszkiel, Julian; Gobetto, Roberto; Baricco, Marcello; Hauback, Bjørn; Klassen, Thomas & Dornheim, Martin (2016). KNH2–KH: a metal amide–hydride solid solution. Chemical Communications. ISSN 1359-7345. 52, s 11760- 11763 . doi: 10.1039/c6cc05777b
Sato, Toyoto; Takagi, Shigeyuki; Deledda, Stefano; Hauback, Bjørn & Orimo, Shin-Ichi (2016). Extending the applicability of the Goldschmidt tolerance factor to arbitrary ionic compounds. Scientific Reports. ISSN 2045-2322. 6:23592 . doi: 10.1038/srep23592 Full text in Research Archive.
Zavorotynska, Olena; Deledda, Stefano & Hauback, Bjørn (2016). Kinetics studies of the reversible partial decomposition reaction in Mg(BH4)2. International journal of hydrogen energy. ISSN 0360-3199. 41(23), s 9885- 9892 . doi: 10.1016/j.ijhydene.2016.02.153
Zavorotynska, Olena; El-Kharbachi, Abdelouahab; Deledda, Stefano & Hauback, Bjørn (2016). Recent progress in magnesium borohydride Mg(BH4)2: Fundamentals and applications for energy storage. International journal of hydrogen energy. ISSN 0360-3199. 41(32), s 14387- 14403 . doi: 10.1016/j.ijhydene.2016.02.015 Full text in Research Archive.
Alcantara, Karina Suarez; Sørby, Magnus Helgerud; Pistidda, Claudio; Karimi, Fahim; Saldan, Ivan; Hauback, Bjørn; Klassen, Thomas & Dornheim, Martin (2015). Synchrotron diffraction studies of hydrogen absorption/desorption on CaH2 + MgB2 Reactive hydride composite mixed with fluorinated compounds. Journal of Physical Chemistry C. ISSN 1932-7447. 119(21), s 11430- 11437 . doi: 10.1021/acs.jpcc.5b01961
Chaudhary, Anna-Lisa; Li, Guanqiao; Matsuo, Motoaki; Orimo, Shin-Ichi; Deledda, Stefano; Sørby, Magnus Helgerud; Hauback, Bjørn; Pistidda, Claudio; Klassen, Thomas & Dornheim, Martin (2015). Simultaneous desorption behavior of M borohydrides and Mg2FeH6 reactive hydride composites (M = Mg, then Li, Na, K, Ca). Applied Physics Letters. ISSN 0003-6951. 107(7) . doi: 10.1063/1.4929340
Frommen, Christoph; Heere, Michael; Riktor, Marit Dalseth; Sørby, Magnus Helgerud & Hauback, Bjørn (2015). Hydrogen storage properties of rare earth (RE) borohydrides (RE = La, Er) in composite mixtures with LiBH4 and LiH. Journal of Alloys and Compounds. ISSN 0925-8388. 645(1), s S155- S159 . doi: 10.1016/j.jallcom.2015.01.113 Full text in Research Archive. Show summary
Mixtures of 6LiBH4–RECl3–3LiH (RE = La, Er) have been produced by mechanochemical milling and their structure, thermal decomposition and reversibility have been studied. Hydrogen desorption starts around 300 °C in both composites. Heating to 400 °C yields LaB6, ErB4 and REH2+δ as major decomposition products. LiBH4 is destabilized by REH2+δ formed through decomposition of the parent borohydrides LiLa(BH4)3Cl and Er(BH4)3, respectively, and its hydrogen release temperature is reduced by 100 °C as compared to pure ball-milled LiBH4. The lanthanum-containing composite releases 4.2 wt.% H between 300 and 350 °C and shows a limited reversibility of ∼20% (340 °C, 10 MPa) probably due to hydrogen uptake by some amorphous boron-containing phases. For 6LiBH4–ErCl3–3LiH about 3 wt.% H is evolved up to 400 °C. Desorption against 0.5 MPa backpressure results in an increased reversibility (∼80%) as compared to vacuum (∼66%). Rehydrogenation (340 °C, 10 MPa) shows the formation of ErH3 and LiBH4 at drastically reduced conditions compared to pure LiBH4 (>400 °C, >10 MPa).
Gosselin, Catherine; Deledda, Stefano; Hauback, Bjørn & Huot, Jacques (2015). Effect of synthesis route on the hydrogen storage properties of 2MgH2–Fe compound doped with LiBH4. Journal of Alloys and Compounds. ISSN 0925-8388. 645(1), s S304- S307 . doi: 10.1016/j.jallcom.2014.12.162 Full text in Research Archive.
Guzik, Matylda N.; Deledda, Stefano; Sørby, Magnus Helgerud; Yartys, Volodymyr & Hauback, Bjørn (2015). New FCC Mg-Zr and Mg-Zr-ti deuterides obtained by reactive milling. Journal of Solid State Chemistry. ISSN 0022-4596. 226, s 237- 242 . doi: 10.1016/j.jssc.2015.03.005 Full text in Research Archive.
Hino, Satoshi; Grove, Hilde; Ichikawa, Takayuki; Kojima, Yoshitsugu; Sørby, Magnus Helgerud & Hauback, Bjørn (2015). Metal aluminum amides for hydrogen storage – Crystal structure studies. International journal of hydrogen energy. ISSN 0360-3199. 40(47), s 16938- 16947 . doi: 10.1016/j.ijhydene.2015.05.012 Full text in Research Archive.
Humphries, Terry David; Takagi, Shigeyuki; Li, Guanqiao; Matsuo, Motoaki; Sato, Toyoto; Sørby, Magnus Helgerud; Deledda, Stefano; Hauback, Bjørn & Orimo, Shin-Ichi (2015). Complex transition metal hydrides incorporating ionic hydrogen: Synthesis and characterization of Na2Mg2FeH8 and Na2Mg2RuH8. Journal of Alloys and Compounds. ISSN 0925-8388. 645(1), s S347- S352 . doi: 10.1016/j.jallcom.2014.12.113
Kalantzopoulos, Georgios N.; Vitillo, JG; Albanese, E.; Pinatel, E.; Civalleri, B.; Deledda, Stefano; Bordiga, S.; Baricco, M & Hauback, Bjørn (2015). Hydrogen storage of Mg-Zn mixed metal borohydrides. Journal of Alloys and Compounds. ISSN 0925-8388. 615, s S702- S705 . doi: 10.1016/j.jallcom.2013.12.258
Kim, Chul; Hwang, Son-Jong; Bowman, Robert C.; Sørby, Magnus Helgerud & Hauback, Bjørn (2015). Deuterium exchange dynamics in Zr2NiD4.8 studied by 2H MAS NMR spectroscopy. Journal of Alloys and Compounds. ISSN 0925-8388. 645(1), s s361- s364 . doi: 10.1016/j.jallcom.2014.12.109
Nakano, Akihiro; Ito, Hiroshi; Bhogilla, Satya Sekhar; Motyka, Theodore; Corgnale, Claudio; Greenway, Scott & Hauback, Bjørn (2015). Research and development for a metal hydride tank with double coil type heat exchanger below 1.0 MPa (G) operation. International journal of hydrogen energy. ISSN 0360-3199. 40(6), s 2663- 2672 . doi: 10.1016/j.ijhydene.2014.12.051
Riktor, Marit Dalseth; Sørby, Magnus Helgerud; Muller, Jiri; Bardají, Elisa Gil; Fichtner, Maximillian & Hauback, Bjørn (2015). On the rehydrogenation of decomposed Ca(BH4)2. Journal of Alloys and Compounds. ISSN 0925-8388. 632, s 800- 804 . doi: 10.1016/j.jallcom.2015.01.243
Saldan, Ivan; Frommen, Christoph; Llamas-Jansa, Isabel; Kalantzopoulos, Georgios N.; Hino, Satoshi; Arstad, Bjørnar; Heyn, Richard H.; Zavorotynska, Olena; Deledda, Stefano; Sørby, Magnus Helgerud; Fjellvåg, Helmer & Hauback, Bjørn (2015). Hydrogen storage properties of γ–Mg(BH4)2 modified by MoO3 and TiO2. International journal of hydrogen energy. ISSN 0360-3199. 40(36), s 12286- 12293 . doi: 10.1016/j.ijhydene.2015.07.082 Show summary
The reversible hydrogen desorption–absorption of γ–Mg(BH4)2 ball milled with MoO3 and TiO2 has been investigated. No mechanochemical interaction between γ–Mg(BH4)2 and TiO2 was observed while for the 1:1 M ratio with MoO3, MoB2 was formed. There was little difference in the properties of γ–Mg(BH4)2 and γ–Mg(BH4)2 ball–milled with 0.02 mol percent TiO2 and MoO3. However, mixing in the same ratio γ–Mg(BH4)2 with TiO2 and MoO3 that had previously been subjected to high energy milling provided significant effects. For these materials, the DSC peaks appeared broader and were shifted to slightly lower temperatures, while the TPD peaks were decreased by ca. 20 °C, as compared to the pure γ–Mg(BH4)2. Faster hydrogen desorption kinetics was observed for the γ–Mg(BH4)2–MoO3 mixture. The reversible hydrogen storage capacity of γ–Mg(BH4)2–TiO2 at 271 °C was found to be 2.4 wt% H2 in the first cycle.
Saldan, Ivan; Llamas-Jansa, Isabel; Hino, Satoshi; Frommen, Christoph & Hauback, Bjørn (2015). Synthesis and thermal decomposition of Mg(BH4)2-TMO (TMO=TiO2;ZrO2;Nb2O5;MoO3) composites. IOP Conference Series: Materials Science and Engineering. ISSN 1757-8981. 77 . doi: 10.1088/1757-899X/77/1/012041
Zavorotynska, Olena; Deledda, Stefano; Li, Guanqiao; Matsuo, Motoaki; Orimo, Shin-Ichi & Hauback, Bjørn (2015). Isotopic Exchange in Porous and Dense Magnesium Borohydride. Angewandte Chemie International Edition. ISSN 1433-7851. 54(36), s 10592- 10595 . doi: 10.1002/anie.201502699
Zavorotynska, Olena; Deledda, Stefano; Vitillo, Jenny G.; Saldan, Ivan; Guzik, Matylda Natalia; Baricco, Marcello; Walmsley, John; Muller, Jiri & Hauback, Bjørn (2015). Combined X-ray and Raman studies on the effect of cobalt additives on the decomposition of magnesium borohydride. Energies. ISSN 1996-1073. 8(9), s 9173- 9190 . doi: 10.3390/en8099173 Show summary
Magnesium borohydride (Mg(BH4)2) is one of the most promising hydrogen storage materials. Its kinetics of hydrogen desorption, reversibility, and complex reaction pathways during decomposition and rehydrogenation, however, present a challenge, which has been often addressed by using transition metal compounds as additives. In this work the decomposition of Mg(BH4)2 ball-milled with CoCl2 and CoF2 additives, was studied by means of a combination of several in-situ techniques. Synchrotron X-ray diffraction and Raman spectroscopy were used to follow the phase transitions and decomposition of Mg(BH4)2. By comparison with pure milled Mg(BH4)2, the temperature for the γ → ε phase transition in the samples with CoF2 or CoCl2 additives was reduced by 10–45 °C. In-situ Raman measurements showed the formation of a decomposition phase with vibrations at 2513, 2411 and 766 cm−1 in the sample with CoF2. Simultaneous X-ray absorption measurements at the Co K-edge revealed that the additives chemically transformed to other species. CoF2 slowly reacted upon heating till ~290 °C, whereas CoCl2 transformed drastically at ~180 °C.
Zavorotynska, Olena; Saldan, Ivan; Hino, Satoshi; Humphries, Terry David; Deledda, Stefano & Hauback, Bjørn (2015). Hydrogen cycling in γ-Mg(BH4)2 with cobalt-based additives. Journal of Materials Chemistry A. ISSN 2050-7488. 3(12), s 6592- 6602 . doi: 10.1039/c5ta00511f
Floriano, R.; Leiva, Daniel Rodrigo; Deledda, Stefano; Hauback, Bjørn & Botta, W.J. (2014). MgH2-based nanocomposites prepared by short-time high energy ball milling followed by cold rolling: A new processing route. International journal of hydrogen energy. ISSN 0360-3199. 39(9), s 4404- 4413 . doi: 10.1016/j.ijhydene.2013.12.209
Grove, Hilde; Rude, Line H.; Jensen, Torben R.; Corno, Marta; Ugliengo, Piero; Baricco, Marcello; Sørby, Magnus Helgerud & Hauback, Bjørn (2014). Halide substitution in Ca(BH4)(2). RSC Advances. ISSN 2046-2069. 4(9), s 4736- 4742 . doi: 10.1039/c3ra46226a Full text in Research Archive.
Humphries, Terry David; Ley, Morten B.; Frommen, Christoph; Munroe, Keelie T.; Jensen, Torben R. & Hauback, Bjørn (2014). Crystal structure and in situ decomposition of Eu(BH4)2 and Sm(BH4)2. Journal of Materials Chemistry A. ISSN 2050-7488. 3(2), s 691- 698 . doi: 10.1039/c4ta04080e Full text in Research Archive.
Humphries, Terry David; Makepeace, Joshua W.; Hino, Satoshi; David, William I.F. & Hauback, Bjørn (2014). Regeneration of sodium alanate studied by powder in situ neutron and synchrotron X-ray diffraction. Journal of Materials Chemistry A. ISSN 2050-7488. 2(39), s 16594- 16600 . doi: 10.1039/c4ta02886d
Jantsky, Laurent; Okamoto, Hiroshi; Thomas, Michael; Karen, Pavel; Hauback, Bjørn; Rosseinsky, Matthew J & Fjellvåg, Helmer (2014). Complex Magnetic Behavior in the PrSr3(Fe1–xCox)3O10−δ n = 3 Ruddlesden–Popper-Type Solid Solution with High Valent Cobalt and Iron. Chemistry of Materials. ISSN 0897-4756. 26(2), s 886- 897 . doi: 10.1021/cm400394c
Kalantzopoulos, Georgios N.; Guzik, Matylda N.; Deledda, Stefano; Heyn, Richard H; Muller, Jiri & Hauback, Bjørn (2014). Destabilization effect of transition metal fluorides on sodium borohydride. Physical Chemistry, Chemical Physics - PCCP. ISSN 1463-9076. 16(38), s 20483- 20491 . doi: 10.1039/c4cp02899f Show summary
The effect of transition metal fluorides on the decomposition of NaBH4 has been investigated for NaBH4 ball milled with TiF3, MnF3 or FeF3. The compounds were examined by thermal programmed desorption with residual gas analysis, thermo gravimetric analysis and volumetric measurements using a Sieverts-type apparatus. The phase formation process during thermal decomposition was studied by in situ synchrotron radiation powder X-ray diffraction on the as-milled powders. NaBF4 was among the products in all mechano-chemical reactions. 11B-NMR spectra analysis gave NaBF4:NaBH4 ratios of 1:150 for Na–Ti, 1:40 for Na–Mn, and 1:10 for Na–Fe. Pure NaBH4 possessed a hydrogen release onset temperature of 430 °C. The hydrogen release in the NaBH4–MnF3 system began as low as 130 °C. FeF3 decreased the onset temperature to 161 °C and TiF3 to 200 °C. TiF3 reacted completely with NaBH4 below 320 °C. All the examined systems have negligible emissions of diborane species. H-sorption studies performed at selected temperatures above 300 °C exhibited relatively fast desorption kinetics. Partial hydrogen re-absorption was observed for the Na–Mn and Na–Fe samples.
Li, Guanqiao; Matsuo, Motoaki; Deledda, Stefano; Hauback, Bjørn & Orimo, Shin-ichi (2014). Dehydriding property of NaBH4 combined with Mg2FeH6. Materials transactions. ISSN 1345-9678. 55(8), s 1141- 1143 . doi: 10.2320/matertrans.MG201404
Olsen, Gerhard H.; Sørby, Magnus Helgerud; Hauback, Bjørn; Selbach, Sverre Magnus & Grande, Tor (2014). Revisiting the crystal structure of rhombohedral lead metaniobate. Inorganic Chemistry. ISSN 0020-1669. 53(18), s 9715- 9721 . doi: 10.1021/ic5012378
Olsen, Jørn Eirik; Karen, Pavel; Sørby, Magnus Helgerud & Hauback, Bjørn (2014). Effect of chloride substitution on the order-disorder transition in NaBH4 and (NaBD4)-B-11. Journal of Alloys and Compounds. ISSN 0925-8388. 587, s 374- 379 . doi: 10.1016/j.jallcom.2013.10.171 Full text in Research Archive.
Olsen, Jørn Erik; Frommen, Christoph; Jensen, Torben R.; Riktor, Marit Dalseth; Sørby, Magnus Helgerud & Hauback, Bjørn (2014). Structure and thermal properties of composites with RE-borohydrides (RE = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Er, Yb or Lu) and LiBH4. RSC Advances. ISSN 2046-2069. 4(4), s 1570- 1582 . doi: 10.1039/c3ra44012e
Qviller, Atle Jorstad; Dennison, A.J.C.; Haug, Halvard; You, Chang Chuan; Hasle, Ida Margrete; Østreng, Erik; Fjellvåg, Helmer; Vorobiev, A.; Hjorvarsson, B; Marstein, Erik Stensrud; Frommen, Christoph & Hauback, Bjørn (2014). Thermal stability of photovoltaic a-Si:H determined by neutron reflectometry. Applied Physics Letters. ISSN 0003-6951. 105(23) . doi: 10.1063/1.4904340 Full text in Research Archive.
Saldan, Ivan; Hino, Satoshi; Humphries, Terry David; Zavorotynska, Olena; Chong, M.; Jensen, C. M.; Deledda, Stefano & Hauback, Bjørn (2014). Structural changes observed during the reversible hydrogenation of Mg(BH4)2 with Ni-based additives. Journal of Physical Chemistry C. ISSN 1932-7447. 118(40), s 23376- 23384 . doi: 10.1021/jp5066677 Full text in Research Archive.
Sato, Toyoto; Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi; Deledda, Stefano; Hauback, Bjørn & Orimo, Shin-ichi (2014). Raman and infrared spectroscopic studies on Li4RuH6 combined with first-principles calculations. Materials transactions. ISSN 1345-9678. 55(8), s 1117- 1121 . doi: 10.2320/matertrans.MG201403
Albanese, E.; Kalantzopoulos, Georgios N.; Vitillo, JG; Pinatel, Eugenio; Civalleri, Bartolomeo; Deledda, Stefano; Bordiga, S.; Hauback, Bjørn & Baricco, Marcello (2013). Theoretical and experimental study on Mg(BH4)2–Zn(BH4)2 mixed borohydrides. Journal of Alloys and Compounds. ISSN 0925-8388. 580, s S282- S286 . doi: 10.1016/j.jallcom.2013.02.165 Full text in Research Archive.
Chatzichristodoulou, C.; Hauback, Bjørn & Hendriksen, P.V. (2013). In situ X-ray and neutron diffraction of the Ruddlesden-Popper compounds (RE2-xSrx)(0.98)(Fe0.8Co0.2)(1-y)MgyO4-delta (RE=La, Pr): Structure and CO2 stability. Journal of Solid State Chemistry. ISSN 0022-4596. 201, s 164- 171 . doi: 10.1016/j.jssc.2013.02.014
Floriano, Ricardo; Leiva, Daniel Rodrigo; Deledda, Stefano; Hauback, Bjørn & Botta, Walter José (2013). Cold rolling of MgH2 powders containing different additives. International journal of hydrogen energy. ISSN 0360-3199. 38(36), s 16193- 16198 . doi: 10.1016/j.ijhydene.2013.10.029
Floriano, Ricardo; Leiva, Daniel Rodrigo; Deledda, Stefano; Hauback, Bjørn & Botta, Walter José (2013). Nanostructured MgH2 Obtained by Cold Rolling Combined with Short-time High-energy Ball Milling. Materials Research. ISSN 1516-1439. 16(1), s 158- 163 . doi: 10.1590/S1516-14392012005000162
Graetz, Jason & Hauback, Bjørn (2013). Recent developments in aluminum-based hydrides for hydrogen storage. MRS bulletin. ISSN 0883-7694. 38(6), s 473- 479 . doi: 10.1557/mrs.2013.107
Heyn, Richard H; Saldan, Ivan; Sørby, Magnus Helgerud; Frommen, Christoph; Arstad, Bjørnar; Bouzga, Aud Mjærum; Fjellvåg, Helmer & Hauback, Bjørn (2013). Structural and spectroscopic characterization of potassium fluoroborohydrides. Physical Chemistry, Chemical Physics - PCCP. ISSN 1463-9076. 15(27), s 11226- 11230 . doi: 10.1039/c3cp52070f Full text in Research Archive. Show summary
Mechanochemical reactions between KBH4 and KBF4 result in the formation of potassium fluoroborohydrides K(BHxF4−x) (x = 0–4), as determined by 11B and 19F solid state NMR. The materials maintain the cubic KBH4 structure. Thermogravimetric (TG) data for a ball-milled sample with KBH4:KBF4 = 3:1 are consistent with only desorption of hydrogen.
Humphries, Terry David; Birkmire, Derek; Hauback, Bjørn; McGrady, G. Sean & Jensen, Craig M. (2013). In situ high pressure NMR study of the direct synthesis of LiAlH4. Journal of Materials Chemistry. ISSN 0959-9428. 1(9), s 2974- 2977 . doi: 10.1039/c3ta10239d Full text in Research Archive.
Humphries, Terry David; Birkmire, Derek; Hauback, Bjørn; McGrady, G. Sean & Jensen, Craig M. (2013). In situ high pressure NMR study of the direct synthesis of NaAlH4. Physical Chemistry, Chemical Physics - PCCP. ISSN 1463-9076. 15(17), s 6179- 6181 . doi: 10.1039/c3cp50777g Full text in Research Archive.
Humphries, Terry David; Kalantzopoulos, Georgios N.; Llamas-Jansa, Isabel; Olsen, Jørn Erik & Hauback, Bjørn (2013). Reversible Hydrogenation Studies of NaBH4 Milled with Ni-Containing Additives. Journal of Physical Chemistry C. ISSN 1932-7447. 117(12), s 6060- 6065 . doi: 10.1021/jp312105w Full text in Research Archive.

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Cai, Xiao-Xiao; Llamas-Jansa, Isabel; Mullet, Steven; Hval, Sverre; Klinkby, Esben; Kittelmann, Thomas; Kanaki, Kalliopi; Hall-Wilton, Richard & Hauback, Bjørn (2013). Preliminary assessment of geant4 HP models and cross section libraries by reactor criticality benchmark calculations. Institute of Electrical and Electronics Engineers ( IEEE ). ISBN 9781479905324. 2 s.

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El-Kharbachi, Abdelouahab; Høgset, A.; Kim, Sangryun; Vajeeston, Ponniah; Sørby, Magnus Helgerud; Fjellvåg, Helmer; Orimo, Shin-ichi & Hauback, Bjørn (2018). Structural and Electrochemical Study of Mixtures of Halogenated-LiBH4 and Amorphous 0.75Li2S·0.25P2S5 for Li- Conducting Solid Electrolytes.
El-Kharbachi, Abdelouahab; Hu, Yang; Mæhlen, Jan Petter; Sørby, Magnus Helgerud; Fjellvåg, Helmer & Hauback, Bjørn (2017). Hydride Materials in All-Solid Li-Ion Cell Configuration.
El-Kharbachi, Abdelouahab; Hu, Yang; Sørby, Magnus Helgerud; Mæhlen, Jan Petter; Fjellvåg, Helmer & Hauback, Bjørn (2017). Contribution of hydride materials to Li-ion battery technology.
El-Kharbachi, Abdelouahab; Hu, Yang; Sørby, Magnus Helgerud; Vullum, Per Erik; Mæhlen, Jan Petter; Fjellvåg, Helmer & Hauback, Bjørn (2017). Mechanistic Properties of MgH2–Based Anode As Derived from Structural Morphology Changes Versus Electrochemical Impedance in a Li-Ion Cell.
El-Kharbachi, Abdelouahab; Hu, Yang; Yoshida, Koji; Sørby, Magnus Helgerud; Fjellvåg, Helmer; Orimo, Shin-Ichi & Hauback, Bjørn (2017). Ionic Properties of the Li(BH4)0.75I0.25 - 0.75Li2S·0.25P2S5 Mixed System for Near Room-Temperature All-Solid Li-Ion Batteries.
El-Kharbachi, Abdelouahab; Hu, Yang; Yoshida, Koji; Sørby, Magnus Helgerud; Ichikawa, Takayuki; Fjellvåg, Helmer; Orimo, Shin-Ichi & Hauback, Bjørn (2017). Hydride materials in all-solid Li-ion cell configuration for room and high temperature applications.
El-Kharbachi, Abdelouahab; Uesato, Hiroki; Yamaguchi, S; Sørby, Magnus Helgerud; Miyaoka, H; Ichikawa, Takayuki; Fjellvåg, Helmer & Hauback, Bjørn (2017). Metal Hydride–Oxide Paired Anode for All-Solid Li-Ion Batteries.
Guzik, Matylda N.; Echevarria-Bonet, Cristina; Sørby, Magnus Helgerud & Hauback, Bjørn (2017). Half-Heusler Phase Formation and Ni atom distribution in M-Ni-Sn (M = Hf, Ti, Zr)System.
Guzik, Matylda N.; Schrade, Matthias; Tofan, Raluca; Berland, Kristian; Gunnæs, Anette Eleonora; Persson, Clas; Sørby, Magnus Helgerud & Hauback, Bjørn (2017). Structural Investigation of Ti1-xHfxNiySn Half-Heusler Compounds.
Hu, Yang; El-Kharbachi, Abdelouahab; Yoshida, Koji; Vajeeston, Ponniah; Sørby, Magnus Helgerud; Orimo, Shin-Ichi; Fjellvåg, Helmer & Hauback, Bjørn (2017). Ionic Properties of the borohydride-sulfide Mixed System for All-Solid Li-Ion Batteries.
Montero, José; Martinsen, Fredrik Aleksander; García-Tecedor, Miguel; Karazhanov, Smagul; Maestre, David; Hauback, Bjørn & Marstein, Erik Stensrud (2017). Photochromic mechanism in oxygen-containing yttrium hydride thin films: An optical perspective. Physical Review B. ISSN 2469-9950. 95(20), s 1- 4 . doi: 10.1103/PhysRevB.95.201301 Full text in Research Archive. Show summary
Oxygen-containing yttrium hydride thin films exhibit photochromic behavior: Transparent thin films reversibly switch from a transparent state to a photodarkened state after being illuminated with UV or blue light. From optical spectrophotometry and ellipsometry measurements of the transparent state and photodarkened state, it is concluded that the photochromic effect can be explained by the gradual growth, under illumination, of metallic domains within the initial wide-band-gap semiconducting lattice. This conclusion is supported by Raman measurements.
Echevarria-Bonet, Cristina; Guzik, Matylda Natalia; Sørby, Magnus Helgerud & Hauback, Bjørn (2016). Composition of n-type Half-Heusler Compounds by SR-PXD.
El-Kharbachi, Abdel; Andersen, Hanne Flåten; Sørby, Magnus Helgerud; Mæhlen, Jan Petter & Hauback, Bjørn (2016). Structural Morphology Effects on the Electrochemical Cycling of MgH2 Anode for Lithium Ion Batteries.
Sørby, Magnus Helgerud; Heere, Michael; Frommen, Christoph & Hauback, Bjørn (2016). Rare-earth borohydrides - crystal structures and in-situ characterization.
Echevarria-Bonet, Cristina; Tofan, Raluca; Schrade, Matthias; Gunnæs, Anette Eleonora; Persson, Clas; Sørby, Magnus Helgerud & Hauback, Bjørn (2015). Enhancement of the thermoelectric properties in nanostructured half-Heusler alloys.
El-Kharbachi, Abdel; Andersen, Hanne Flåten; Sørby, Magnus Helgerud; Mæhlen, Jan Petter & Hauback, Bjørn (2015). Contribution of the electrode morphology to the electrochemical cycling of MgH2-based anode for Li-ion batteries.
Karazhanov, Smagul; Mongstad, TT; Martinsen, Fredrik Aleksander; Amenedo, J. M.; Zayim, E. O.; Mohseni, A.; You, C; Mæhlen, Jan Petter; Galeckas, Augustinas; Moldarev, D; Molff, M; Pishtshev, Aleksandr; Hauback, Bjørn; Subrahmanyam, A & Marstein, Erik Stensrud (2015). Photochromic Materials & Applications.
Olsen, Gerhard Henning; Sørby, Magnus Helgerud; Hauback, Bjørn; Selbach, Sverre Magnus & Grande, Tor (2014). Revisiting rhombohedral lead metaniobate – Crystal structure and functional properties.
Song, Xin; Persson, Clas; Norby, Truls; Flage-Larsen, Espen; Karlsen, Ole Bjørn; Hansen, Vidar; Gunnæs, Anette Eleonora; Prytz, Øystein; Løvvik, Ole Martin; Finstad, Terje; Valset, Kjetil; Cui, Xuemei; Taftø, Johan; Fjeld, Harald; Hauback, Bjørn & Schrade, Matthias (2014). Conversion of Heat and Energy: Thermoelectrics.

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Published Nov. 4, 2010 12:18 PM - Last modified May 24, 2013 11:23 AM

Bjørn Hauback

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