Disputation: Deniz Avsar

Doctoral candidate Deniz Avsar at the Department of Chemistry, Faculty of Mathematics and Natural Sciences, is defending the thesis "Speciation and Extraction of Cr(VI) Compounds from Acidic Nitro-phosphate Solutions Using Conventional and Radiochemical Methods" for the degree of Philosophiae Doctor. 

Image may contain: A person (Deniz) looking straight at the camera. They have short brown hair and are wearing a black crewneck shirt.

Deniz Avsar

The Disputation will be live streamed for everyone else.
The livestream will be activated 15 minutes before the Defense starts.

Trial lecture

March 7th, 10:15 AM, Auditorium 3, Chemistry building

Trial lecture title: "Production of Molybdenum-99 (Mo-99) for pharmaceutical purposes"

Kreeringssammendrag/Conferral summary 

Doktorgradskandidaten undersøkte spesiering av krom og reduksjonsmekanismene til Cr(VI) i sure nitrofosfatløsninger med høyt saltinnhold for å bedre forstå spesiets oppførsel, mobilitet og miljøpåvirkning. Denne kunnskapen er avgjørende for å optimalisere separasjon av krom fra slike komplekse løsninger og forbedre gjenvinningsprosesser for krom. I tillegg evaluerer studien ulike ekstraksjonssystemer for effektiv Cr(VI)-separasjon og utforsker bruken av radioaktive sporstoffer for å forbedre hydrometallurgiske applikasjoner.

Main research findings

Phosphorus is essential for life and a key ingredient in the fertilizers that support global food production. However, as high-quality phosphorus sources become scarce, industries are turning to alternative materials that often contain unwanted impurities. This research investigates the removal and recovery of such impurities—especially the harmful form of chromium known as Cr(VI)—from acidic nitro-phosphate solutions. Under these harsh conditions, we found that Cr(VI) is unstable and converts to Cr(III), a much less toxic form that can even act as a nutrient. To better understand this process, we investigated the key factors influencing its reduction. 

In addition, we explored various extraction methods and discovered that the extraction agent Cyanex 923 works particularly well for removing and recovering Cr(VI).  We also produced radioactive tracers of lead (Pb) and arsenic (As) to further refine our process. Overall, this research contributes to a cleaner and more sustainable fertilizer production by turning a toxic challenge into an opportunity for resource recovery. 

Candidate contact information

E-post: deniz.avsar@kjemi.uio.no

Phone: +47 967 47 183

 

Adjudication committee

Professor Kerstin Forsberg
Royal Institute of Technology, Sweden

Professor Teodora Retagan Vollmer
Chalmers University of Technology, Sweden

Professor Harald Johan Walderhaug
Department of Chemistry, University of Oslo, Norway

Supervisors

Professor Jon Petter Court Omtvedt
Department of Chemistry, University of Oslo, Norway

Senior advisor Dag Øistein Eriksen
Department of Chemistry, University of Oslo, Norway

Chair of defence

Professor Ola Nilsen
Department of Chemistry, University of Oslo, Norway

Published Feb. 21, 2025 8:00 AM - Last modified Mar. 13, 2026 10:26 AM