Solid-solid interfaces as critical regions in rocks and materials

Probing forces, electrochemical reactions, friction and reactivity.

About the project

The overall strength of granular materials and porous rocks is often associated with processes that take place in fluid-filled contacts between individual solid grains. To recognize these processes and to be able to modify them, we need analytical methods that investigate the relevant interfaces at a nanoscale. In this experimental project, we study the interfaces with the Surface Forces Apparatus (SFA).

SFA measures surface forces acting at nanoscale surface separations between two macroscopic surfaces (a contact radius diameter is approximately 100 µm). An in-situ sensing SFA modification developed by the Applied Interface Physics group at the Vienna University of Technology allows monitoring of the measured forces in real-time, owing to the addition of strain gage-based force-measuring sensors. That expands the applications of the SFA and enables force measurements without bringing the surfaces out of contact. Owing to the use of the white light interferometry technique coupled to the SFA, we can also simultaneously visualize recrystallization, dissolution, and growth of the two confining surfaces.

Objectives

The overarching goal of this project is to recognize which processes make the interfaces weak, and how to convert the weak interfaces into strong ones. Although we see destructive effects of weak interfaces at a macroscopic scale (earthquakes, rock compaction and subsidence, and general material failure), the very mechanisms governing the interfacial strength are frequently operating at much smaller scales (10-9 m). The SFA technique lets us probe various nanoscale processes occurring between two confined solid surfaces and assess what impacts the interfacial strength the most. 

Outcomes

In the first year of this project, we focused on the very composition of confined solid-solid interfaces filled with electrolytes or organic solutions. We showed that the biding of soluble organic molecules could be modulated by the addition of inorganic ions, which have a different affinity to both adsorb onto the solid confining walls and to form complexes with the functional groups of the organics. Using the electrochemical SFA (EC-SFA), we further studied the transport of organic and inorganic ions into and out of a nano-sized confined gap. With the EC-SFA, we can rapidly change the surface charge of one of the confining surfaces and visualize how the ions are transported. In this work, we observed a number of interesting metastable charge regulation pathways emerging before the charge equilibrium is achieved in a nano-sized gap between two solid surfaces. 

Read more updates from the project here!

A plot of gap thickness (nm) vs time (s) showing two peaks representing a potential switch (left) and potential back (right) with the zone of counterions removal and slow refilling of ion pair in between.
Electrochemically induced transport of ions out of and into a nanosized gap between two solid surfaces.

Financing

The Research Council of Norway, FRIPRO Mobility Grant

Cooperation

  • The Njord Center, University of Oslo, Norway
  • Vienna University of Techonology, Vienna, Austria

Seals of project participants.

 

Publications

  • Dziadkowiec, J., & Ro̷yne, A. (2020). Nanoscale Forces between Basal Mica Surfaces in Dicarboxylic Acid Solutions: Implications for Clay Aggregation in the Presence of Soluble Organic Acids. Langmuir, 49, 14978–14990.
  • Cheng, H.-W., Dziadkowiec, J., Wieser, V., Imre, M., Valtiner, M. Real-time Visualization of Metastable Charge Regulation Pathways in Molecularly Confined Slit Geometries. Under review (preprint: https://arxiv.org/abs/2104.01157).
  • Dziadkowiec, Joanna; Cheng, Hsiu-Wei; Ludwig, Michael; Ban, Matea; Tausendpfund, Timon Pascal & von Klitzing, Regine [Show all 8 contributors for this article] (2022). Cohesion Gain Induced by Nanosilica Consolidants for Monumental Stone Restoration. Langmuir. ISSN 0743-7463. doi: 10.1021/acs.langmuir.2c00486.
  • Dziadkowiec, Joanna; Ban, Matea; Javadi, Shaghayegh; Jamtveit, Bjørn & Røyne, Anja (2021). Ca2+ ions decrease adhesion between two (104) calcite surfaces as probed by Atomic Force Microscopy. ACS Earth and Space Chemistry. ISSN 2472-3452. 5(10), p. 2827–2838. doi: 10.1021/acsearthspacechem.1c00220. Full text in Research Archive
  • Dziadkowiec, Joanna & Røyne, Anja (2020). Nanoscale Forces between Basal Mica Surfaces in Dicarboxylic Acid Solutions: Implications for Clay Aggregation in the Presence of Soluble Organic Acids. Langmuir. ISSN 0743-7463. 36(49), p. 14978–14990. doi: 10.1021/acs.langmuir.0c02290. Full text in Research Archive

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  • Dziadkowiec, Joanna; Ban, Matea; Javadi, Shaghayegh; Jamtveit, Bjørn & Røyne, Anja (2021). Ion-specific adhesion between brittle calcite surfaces.
  • Dziadkowiec, Joanna (2021). Nucleation in confinement – experiments in surface forces apparatus.
  • Dziadkowiec, Joanna; Zareeipolgardani, Bahareh; Cheng, Hsiu-Wei; Dysthe, Dag Kristian; Røyne, Anja & Valtiner, Markus (2021). Forces between reactive surfaces.
  • Dziadkowiec, Joanna & Røyne, Anja (2021). Do soluble organic acids bind to basal mica surfaces?
  • Dziadkowiec, Joanna; Zareeipolgardani, Bahareh; Dysthe, Dag Kristian & Røyne, Anja (2020). Confined Nucleation of Calcium Carbonate Studied in the Surface Forces Apparatus.
  • Haffner, Fernanda; Couturier, Marion & Dziadkowiec, Joanna (2020). Crystals: From rock candy to rock(et) science. Esperluette. June 2020.
  • Dziadkowiec, Joanna; Cheng, Hsiu-Wei; Røyne, Anja & Valtiner, Markus (2020). Interactions between reactive mineral surfaces studied with the surface forces apparatus.
  • Dziadkowiec, Joanna; Cheng, Hsiu-Wei; Røyne, Anja & Valtiner, Markus (2020). Interfacial processes at dissimilarly charged mineral surfaces in contact – a surface forces apparatus study.
  • Dziadkowiec, Joanna; Zareeipolgardani, Bahareh; Bratvold, Jon E.; Nilsen, Ola; Dysthe, Dag Kristian & Røyne, Anja (2019). Long-range repulsive forces between reactive calcite surfaces are generated due to nucleation in a confined solution.
  • Dziadkowiec, Joanna (2019). (CaCO3) Nucleation in confinement.
  • Dziadkowiec, Joanna; Javadi, Shaghayegh & Røyne, Anja (2019). Contacts between reactive surfaces.
  • Dziadkowiec, Joanna (2019). Interactions between mineral surfaces studied with the surface forces apparatus.

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Published Apr. 9, 2021 2:58 PM - Last modified Nov. 4, 2021 11:06 AM