2D materials beyond graphene (completed)

The primary objective is to establish fundamental relationships between the functional properties and the defect chemistry of 2D materials Beyond graphene.

About the Project

Two-dimensional (2D) materials are emerging as a novel class of functional materials for the miniaturization of electronic and electrochemical devices. They pave the way for electrochemical capacitors with energy densities approaching that of Li-ion batteries due to stacking efficiency, photovoltaic devices with strong light matter interactions and novel transistor architectures - technology that would represent a significant breakthrough for renewable energy storage and conversion. The project seeks fundamental understanding of the defect chemistry and functional properties of 2D materials, encompassing charged point defects as well as clusters in the material and at its highly influential interfaces (surface, edge, inter-layer and substrate).

The project builds upon a fabrication procedure recently demonstrated by the applicants for 2D MoS2, involving PVD techniques and post treatment in H2S at elevated temperature. MoS2 and Ga2S2 will serve as model systems, and other 2D materials and ultra thin films will be pursued, e.g., WSe2, MnO2, TiOxNy. First-principles calculations will be combined with Advanced characterization of the prepared 2D films to elucidate the defect chemistry of the materials, including charge compensation mechanisms for intrinsic and extrinsic defects in the material and interfaces. An electrical characterization setup for 2D films under controlled temperature and atmosphere will be developed. 2D heterostucture devices will be constructed to demonstrate application Properties.

The project will be managed by SINTEF with partners at University of Oslo and University of Luxembourg

 

Financing

The project is funded by Research Council of Norway, Young Research talent under FRINATEK program, project number 262274

Publications

  • Polfus, Jonathan (2023). One-dimensional carbon chains encapsulated in hollandite. Communications chemistry. ISSN 2399-3669. 6(1). doi: 10.1038/s42004-023-01011-3. Full text in Research Archive
  • Barragan-Yani, Daniel; Polfus, Jonathan M. & Wirtz, Ludger (2022). Native defects in monolayer GaS and GaSe: Electrical properties and thermodynamic stability. PHYSICAL REVIEW MATERIALS. ISSN 2475-9953. 6(11). doi: 10.1103/PhysRevMaterials.6.114002. Full text in Research Archive
  • Polfus, Jonathan M.; Benthem, Marta; Ali, Ayaz; Barragan-Yani, Daniel; Vullum, Per Erik & Sunding, Martin Fleissner [Show all 9 contributors for this article] (2021). Temperature-Dependent Adhesion in van der Waals Heterostructures. Advanced Materials Interfaces. ISSN 2196-7350. 8(20). doi: 10.1002/admi.202100838. Full text in Research Archive
  • Polfus, Jonathan M. & Jayasayee, Kaushik (2019). Robust nanocomposites of a-Fe2O3 and N-doped graphene oxide: Interfacial bonding and chemisorption of H2O. Carbon. ISSN 0008-6223. 152, p. 497–502. doi: 10.1016/j.carbon.2019.05.033. Full text in Research Archive
  • Sun, Xinwei; Xu, Kaiqi; Fleischer, Christian; Liu, Xin; Grandcolas, Mathieu & Strandbakke, Ragnar [Show all 9 contributors for this article] (2018). Earth-abundant electrocatalysts in proton exchange membrane electrolyzers. Catalysts. ISSN 2073-4344. 8:657(12), p. 1–41. doi: 10.3390/catal8120657. Full text in Research Archive

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  • Barragan-Yani, Daniel & Wirtz, Ludger (2021). Native defects in monolayer GaS and GaSe.
  • Benthem Muñiz, Marta; Ali, Ayaz; Polfus, Jonathan & Belle, Branson (2019). 2D crystal temperature dependent adhesion in the development of Van der Waals heterostructures .
  • Belle, Branson; Xing, Wen; Stange, Marit Synnøve Sæverud; S. Azar, Amin; Sunding, Martin Fleissner & Polfus, Jonathan M. (2018). Scalable MoS2 growth via Mo sputtering and post H2S treatment.
  • Fleischer, Christian; Bjørheim, Tor Svendsen & Norby, Truls Eivind (2018). Point Defects in Transition Metal Dichalcogenides.
  • Fleischer, Christian; Polfus, Jonathan M.; Bjørheim, Tor Svendsen & Norby, Truls Eivind (2018). Defect Chemistry of Few- and Monolayer MoS2.
  • Fleischer, Christian; Bjørheim, Tor Svendsen; Polfus, Jonathan M. & Norby, Truls Eivind (2018). Point Defects in Monolayer MoS2.
  • Benthem, Marta (2020). Direct Measurement of Adhesion between 2D Materials using Atomic Force Microscopy. École Polytechnique Fédérale de Lausanne.

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Published Sep. 13, 2017 12:47 PM - Last modified Feb. 7, 2023 3:00 AM

Contact

Project leader:

Professor Truls Norby

+47 22840654

Administrative Officer:

Xuemei Cui

+47 22 84 06 64

FASE
Forskningsparken
Gaustadalleen 21
NO-0349 Oslo
Norway
Phone: +47 22840664

Participants

Detailed list of participants