Clemens Petersen

• Andreassen, Magnus; Rosnes, Andreas; Petersen, Clemens; Schenk, Richard Justin; Both, Kevin Gregor & Bergum, Kristin [Vis alle 7 forfattere av denne artikkelen] (2026). Combinatorial Synthesis and Characterization of Lattice-Matched Ga2O3–Cr2O3 and Ga2O3–V2O3 Sesquioxide Alloys for Ultrawide-Bandgap Semiconductor Applications. Physica Status Solidi (a) applications and materials science. ISSN 1862-6300. 223(15). doi: 10.1002/pssa.70437. Fulltekst i vitenarkiv Vis sammendrag

  Gallium sesquioxide is a wide‐bandgap semiconductor of high interest for power electronics and deep UV‐sensing applications. The α‐phase ( E g  = 5.6 eV) can be synthesized with excellent crystal quality on isostructural Al 2 O 3 substrates, removing the need for expensive homoepitaxial growth that is required for the thermodynamically stable β‐phase ( E g  = 4.9 eV). Here, continuous composition spread material libraries of (Ga 1‐ x V x ) 2 O 3 and (Ga 1‐ x Cr x ) 2 O 3 with 0.05 <  x  < 0.45 are synthesized by pulsed laser deposition, and characterized structurally and optically with the aim of decreasing the optical absorption edge of α‐Ga 2 O 3 to expand the range of potential optoelectronic applications. The (Cr x Ga 1‐ x ) 2 O 3 material library remained stable in the rhombohedral α‐phase throughout the investigated compositional range, exhibiting high crystal quality with minimal changes to the unit cell parameters. A systematic shift in optical absorption edge from 5.5 to 3.9 eV is observed, as determined by spectrophotometry. The (Ga 1‐ x V x ) 2 O 3 material library exhibits a systematic shift from 5.2 to 2.9 eV with increasing x V , but a region of decreased crystal quality is observed for 0.11 ≤  x V  ≤ 0.20. Additionally, a secondary V 2 O 5 phase is observed for x V  > 0.23. Overall, bandgap engineering of α‐(Ga 1‐ x V x ) 2 O 3 and α‐(Ga 1‐ x Cr x ) 2 O 3 is demonstrated, and chromium substitution is identified as especially promising due to high crystallinity and systematic change of optical absorption edge.

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