Evgeniy Redekop

Image of Evgeniy Redekop
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Room ØU40
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Visiting address Sem Sælands vei 26 Kjemibygningen 0371 OSLO
Postal address Postboks 1126 Blindern 0318 OSLO
Other affiliations The International Summer School (Student)

The overarching goal of my research is to unravel the molecular mechanisms that underpin sustainability-relevant catalytic reactions and to utilize this knowledge for guiding the development of novel nano-structured materials. My primary experimental methodology relies on time-resolved, perturbation-enhanced techniques in catalytic kinetics (TAP, CTK, ZLC) and in situ spectroscopy (AP-XPS, IR, Raman, XAS). Experimental studies are combined with multi-scale modeling in order to achieve comprehensive understanding of relevant physico-chemical phenomena though rigorous data interpretation. Specific catalytic reactions and materials of interest currently include zeolite and MOF-catalyzed alkene transformations, metal- and oxide-catalyzed hydrogenation of carbon dioxide, as well as selective oxidation reactions on bimetallic surfaces and complex metal oxides. In tandem with application-driven research, we are investigating the fundamental aspects of dynamic processes in reaction/diffusion systems and developing next-generation tools for materials characterization.

Tags: Catalysis, SMN, Chemistry, Energy

Publications

Ping Liu, Evgeniy A. Redekop, Xiang Gao, Wen-Chi Liu, Unni Olsbye, Gabor A. Somorjai, Oligomerization of Light Olefins Catalyzed by Brnsted-Acidic Metal Organic Framework-808, J. Am. Chem. Soc., 2019, DOI: 10.1021/jacs.9b03867

Matthias Filez, Evgeniy A. Redekop, Jolien Dendooven, Ranjith K. Ramachandran, Eduardo Solano, Unni Olsbye, Bert M. Weckhuysen, Vladimir V. Galvita, Hilde Poelman, Christophe Detavernier, Guy B. Marin, Formation and Functioning of Bimetallic Nanocatalysts: The Power of Xray Probes, Angew Chem Int Ed., 2019, DOI: 10.1002/anie.201902859

Christian Reece, Evgeniy A. Redekop, Stavros Karakalos, Cynthia M. Friend, and Robert. J. Madix, Crossing the great divide between single-crystal reactivity and actual catalyst selectivity with pressure transients, Nature Catalysis, 2018, 1, 852859

Matthias Filez, Hilde Poelman, Evgeniy A. Redekop, Vladimir V. Galvita, Konstantinos Alexopoulos, Maria Meledina, Ranjith K. Ramachandran, Jolien Dendooven, Christophe Detavernier, Gustaaf VanTendeloo, Olga V. Safonova, Maarten Nachtegaal, Bert M. Weckhuysen, Guy B. Marin, Kinetics of Lifetime Changes in Bimetallic Nanocat-alysts Revealed by Quick X-ray Absorption Spectroscopy, Angew Chem Int. Ed., 2018, 57, 12430-12434

Stephanie Saerens, Maarten Sabbe, Vladimir V. Galvita, Evgeniy A. Redekop, Marie-Franoise Reyniers, Guy B. Marin, The positive role of hydrogen on the dehydrogenation of propane on Pt(111), ACS Catal., 2017, 7, 74957508

Evgeniy A. Redekop, Stephanie Saerens, Vladimir V. Galvita, Isabel Prieto Gonzlez, Maarten Sabbe, Vitaliy Bliznuk, Marie-Franoise Reyniers, Guy B. Marin, Early stages in the formation and burning of graphene on a Pt/Mg(Al)Ox dehydrogenation catalyst: A temperature- and time-resolved study, J. Cat., 2016, 344, 482-495

Gregory S Yablonsky, Evgeniy A Redekop, Denis Constales, John T Gleaves, Guy B. Marin, Rate Reactivity Model: A New Theoretical Basis for Systematic Kinetic Characterization of Heterogeneous Catalysts, Int. J. Chem. Kinet., 2016, 48(6), 304-317

Matthias Filez, Evgeniy A Redekop, Vladimir V Galvita, Hilde Poelman, Maria Meledina, Stuart Turner, Gustaaf Van Tendeloo, Alexis T Bell, Guy B Marin, The role of hydrogen during PtGa nanocatalyst formation, PCCP, 2016, 18(4), 3234-3243

Matthias Filez, Evgeniy A. Redekop, Hilde Poelman, Vladimir V. Galvita, Maria Meledina, Stuart Turner, Gustaaf Van Tendeloo, Alexis T Bell, Guy B Marin, One-pot synthesis of Pt catalysts based on layered double hydroxides: an application in propane dehydrogenation , Catal. Sci. Tech., 2016, 6, 1863-1869

Stanislas M. Pietrzyk, Evgeniy A. Redekop, Gregory S. Yablonsky, Guy B. Marin, Precise kinetic measurements and spatial uniformity of catalytic beds, Chem. Eng. Sci., 2015, 134, 367373

Matthias Filez, Evgeniy A. Redekop, Hilde Poelman, Vladimir V. Galvita, Guy B. Marin, Advanced Elemental Characterization during PtIn Catalyst Formation by Wavelet Transformed X-ray Absorption Spectroscopy, Anal. Chem., 2015, 87(6), 35203526

Matthias Filez, Evgeniy Redekop, Hilde Poelman, Vladimir Galvita, Ranjith Ramachandran, Jolien Dendooven, Christophe Detavernier, Guy B. Marin, Unravelling the formation of Pt-Ga alloyed nanoparticles on calcined Ga-modi ed hydrotalcites by in situ XAS, ACS Chem. Mater., 2014, 26, 5936-5949

Evgeniy A. Redekop, Vladimir V. Galvita, Hilde Poelman, Vitaliy Bliznuk, Christophe Detavernier, and Guy B. Marin, Delivering a Modifying Element to Metal Nanoparticles via Support: PtGa Alloying during the Reduction of Pt/Mg(Al,Ga)Ox Catalysts and Its E ects on Propane Dehydrogenation, ACS Catal., 2014, 4 (6), pp 1812-1824

Evgeniy A. Redekop, Gregory S. Yablonsky, Denis Constales, Palghat A. Ramachandran, John T. Gleaves, Guy B. Marin, Elucidating complex catalytic mechanisms based on transient pulse-response kinetic data, Chem. Eng. Sci., 2014, 110

Evgeniy A. Redekop, Gregory S. Yablonsky, Vladimir V. Galvita, Denis Constales, Rebecca Fushimi, John T. Gleaves, and Guy B. Marin, Momentary Equilibrium in Transient Kinetics and Its Application for Estimating the Concentration of Catalytic Sites, Ind. Eng. Chem. Res., 2013, 52 (44), 15417-15427

Evgeniy Redekop, Gregory Yablonsky, Denis Constales, Palghat Ramachandran, Catherine Pherigo, John Gleaves, The Y-Procedure methodology for the interpretation
of transient kinetic data: Analysis of irreversible adsorption, Chem. Eng. Sci., 2011, 66, 6441-6452

Xiaolin Zheng, Gabriel M. Veith, Evgeniy Redekop, Cynthia Lo, Gregory Yablonsky, John T. Gleaves, Oxygen and CO Adsorption on Au/SiO2 Catalysts Prepared
by Magnetron Sputtering: The Role of Oxygen Storage, Ind. Eng. Chem. Res., 2010, 49 (21), 10428-10437

Colin P. White, Janet Braddock-Wilking, Joyce Y. Corey, Evgeniy Redekop, et al., Activation of Group 14 El-H Bonds at Platinum(0), Organometallics, 2007, 26,
1996-2004

Published May 13, 2015 10:17 AM - Last modified July 26, 2019 3:05 PM

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