Evgeniy Redekop

Image of Evgeniy Redekop
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Room ØU40
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Visiting address Sem Sælands vei 26 Kjemibygningen 0371 OSLO
Postal address Postboks 1126 Blindern 0318 OSLO

At the University of Oslo, I am investigating the kinetics of alkene methylation catalyzed summary by nanoporous solid Brnsted acids such as zeolites and aluminophosphates. Alkene methylation steps are crucial for the chemistry of Methanol-To-Ole ns (MTO) and Methanol-To-Hydrocarbons (MTH) catalytic processes by which methanol, a promising platform molecule, can be conversted to value added chemicals and fuels. Our group investigates these reactions by combining ab initio modeling, materials synthesis, and kinetic characterization.

We are developing predictive structure-activity dependencies in a series of controlled "one-parameter variation" studies, which are expressed by a set of simple catalyst descriptors. In parallel, we are developing the methodology of time-resolved kinetic characterization beyond the state-of-the-art to better understand the relationships between materials' nanostructures and their reactivity towards gas molecules. To this goal, I am curating the development and operation of the Temporal Analysis of Products (TAP) facility at UiO.

Tags: Catalysis, SMN, Chemistry, Energy

Publications

Evgeniy A. Redekop, Stephanie Saerens, Vladimir V. Galvita, Isabel Prieto Gonzlez, Maarten Sabbe, Vitaliy Bliznuk, Marie-Franoise Reyniers, Guy B. Marin, Early stages in the formation and burning of graphene on a Pt/Mg(Al)Ox dehydrogenation catalyst: A temperature- and time-resolved study, J. Cat., 2016, 344, 482-495

Gregory S Yablonsky, Evgeniy A Redekop, Denis Constales, John T Gleaves, Guy B. Marin, RateReactivity Model: A New Theoretical Basis for Systematic Kinetic Characterization of Heterogeneous Catalysts, Int. J. Chem. Kinet., 2016, 48(6), 304-317

Matthias Filez, Evgeniy A Redekop, Vladimir V Galvita, Hilde Poelman, Maria Meledina, Stuart Turner, Gustaaf Van Tendeloo, Alexis T Bell, Guy B Marin, The role of hydrogen during PtGa nanocatalyst formation, PCCP, 2016, 18(4), 3234-3243

Matthias Filez, Evgeniy A. Redekop, Hilde Poelman, Vladimir V. Galvita, Maria Meledina, Stuart Turner, Gustaaf Van Tendeloo, Alexis T Bell, Guy B Marin, One-pot synthesis of Pt catalysts based on layered double hydroxides: an application in propane dehydrogenation , Catal. Sci. Tech., 2016, 6, 1863-1869

Stanislas M. Pietrzyk, Evgeniy A. Redekop, Gregory S. Yablonsky, Guy B. Marin, Precise kinetic measurements and spatial uniformity of catalytic beds, Chem. Eng. Sci., 2015, 134, 367373

Matthias Filez, Evgeniy A. Redekop, Hilde Poelman, Vladimir V. Galvita, Guy B. Marin, Advanced Elemental Characterization during PtIn Catalyst Formation by Wavelet Transformed X-ray Absorption Spectroscopy, Anal. Chem., 2015, 87(6), 35203526

Matthias Filez, Evgeniy Redekop, Hilde Poelman, Vladimir Galvita, Ranjith Ramachandran, Jolien Dendooven, Christophe Detavernier, Guy B. Marin, Unravelling the formation of Pt-Ga alloyed nanoparticles on calcined Ga-modi ed hydrotalcites by in situ XAS, ACS Chem. Mater., 2014, 26, 5936-5949

Evgeniy A. Redekop, Vladimir V. Galvita, Hilde Poelman, Vitaliy Bliznuk, Christophe Detavernier, and Guy B. Marin, Delivering a Modifying Element to Metal Nanoparticles via Support: PtGa Alloying during the Reduction of Pt/Mg(Al,Ga)Ox Catalysts and Its E ects on Propane Dehydrogenation, ACS Catal., 2014, 4 (6), pp 1812-1824

Evgeniy A. Redekop, Gregory S. Yablonsky, Denis Constales, Palghat A. Ramachandran, John T. Gleaves, Guy B. Marin, Elucidating complex catalytic mechanisms based on transient pulse-response kinetic data, Chem. Eng. Sci., 2014, 110

Evgeniy A. Redekop, Gregory S. Yablonsky, Vladimir V. Galvita, Denis Constales, Rebecca Fushimi, John T. Gleaves, and Guy B. Marin, Momentary Equilibrium in Transient Kinetics and Its Application for Estimating the Concentration of Catalytic Sites, Ind. Eng. Chem. Res., 2013, 52 (44), 15417-15427

Evgeniy Redekop, Gregory Yablonsky, Denis Constales, Palghat Ramachandran, Catherine Pherigo, John Gleaves, The Y-Procedure methodology for the interpretation
of transient kinetic data: Analysis of irreversible adsorption, Chem. Eng. Sci., 2011, 66, 6441-6452

Xiaolin Zheng, Gabriel M. Veith, Evgeniy Redekop, Cynthia Lo, Gregory Yablonsky, John T. Gleaves, Oxygen and CO Adsorption on Au/SiO2 Catalysts Prepared
by Magnetron Sputtering: The Role of Oxygen Storage, Ind. Eng. Chem. Res., 2010, 49 (21), 10428-10437

Colin P. White, Janet Braddock-Wilking, Joyce Y. Corey, Evgeniy Redekop, et al., Activation of Group 14 El-H Bonds at Platinum(0), Organometallics, 2007, 26,
1996-2004

Published May 13, 2015 10:17 AM - Last modified Feb. 23, 2017 4:12 PM

Research groups